87323-96-4

Basic information

• Product Name: C₂H₄⁽²⁾HO₄S^(1-)*Na⁽¹⁺⁾
• Synonyms: C₂H₄⁽²⁾HO₄S^(1-)*Na⁽¹⁺⁾
• CAS NO: 87323-96-4
• Molecular Weight: 149.107
• Mol File: 87323-96-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂H₄⁽²⁾HO₄S^(1-)*Na⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₂H₄⁽²⁾HO₄S^(1-)*Na⁽¹⁺⁾(87323-96-4)
• EPA Substance Registry System: C₂H₄⁽²⁾HO₄S^(1-)*Na⁽¹⁺⁾(87323-96-4)

Safety Data

• Hazardous Substances Data: 87323-96-4(Hazardous Substances Data)

Upstream product

• 78303-70-5 2-hydroxyethane-1-sulfonyl chloride 
• 110-86-1 pyridine 

Relevant articles and documents

Organic sulfur mechanisms. 24. Preparation and reaction of 2-hydroxyethanesulfonyl chloride, the first hydroxyalkanesulfonyl chloride

2-Hydroxyethanesulfonyl chloride (1a) is readily made by reaction of an aqeous solution of 2-mercaptoethanol (4a) with chlorine.This is the first clearly proved preparation of a compound which is both an alcohol and a sulfonyl chloride.Reactions of 1a with water and alcohols evidently proceed largely by intramolecular cyclization to the transient β-sultone (2a), which then undergoes nucleophilic ring opening to form the products.In the presence of tertiary amines a minor but significant part of the reaction is shown by deuterium labelling to proceed via hydroxymethylsulfene (14), the principal reaction of which is simply to add the alcohol or water; only a small part, if any, of the sulfene (14) loses the hydroxyl group to give the ethenesulfonate derivatives (13 or 22).Aqueous chlorination of 3-mercapto-1-propanol gave 3-chloro-1-propanesulfonyl chloride (5a) and 1,3-propane sultone (2b) with no sign of any 3-hydroxy-1-propanesulfonyl chloride (1b).A mechanism for the aqueous chlorination process invoking a cyclic chlorooxasulfoxonium ion (27) is discussed.