87327-59-1

Basic information

• Product Name: acetoxyacetic acid acetic acid-anhydride
• Synonyms: acetoxyacetic acid acetic acid-anhydride
• CAS NO: 87327-59-1
• Molecular Weight: 160.127
• Mol File: 87327-59-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: acetoxyacetic acid acetic acid-anhydride(CAS DataBase Reference)
• NIST Chemistry Reference: acetoxyacetic acid acetic acid-anhydride(87327-59-1)
• EPA Substance Registry System: acetoxyacetic acid acetic acid-anhydride(87327-59-1)

Safety Data

• Hazardous Substances Data: 87327-59-1(Hazardous Substances Data)

Downstream Products

• 13831-30-6 acetoxyacetic acid 
• 108-24-7 acetic anhydride 

Relevant articles and documents

Short path syntheses of α-diozonides by sequential ozonolyses of acetylenes and O-methyl oximes

Ozonolyses of but-2-yne 1 in the presence of added carbonyl compounds 3 afford α-oxo ozonides 4. Subsequent cycloadditions between ozonides 4 and cyclohexanone oxide 6, generated in situ by ozonolysis of O-methylcyclohexanone oxime, yield in turn α-diozonides 7 into which have been incorporated the carbon skeletons of all three substrates involved. Ozonolyses of acyloxy-substituted but-2-ynes 9 yield the corresponding bicyclic α-oxo ozonides 11 which subsequently participate in analogous cycloadditions with 6 to produce the corresponding α-diozonides 12. X-Ray crystallographic analysis of the crystalline diozonide 12a shows that it has been formed exclusively by exo-addition of 6 to 11a.