873932-12-8

Basic information

• Product Name: NiBr₂(P(C₆H₅)2C₆H₄CCH₃NC₉H₆N)
• CAS NO: 873932-12-8
• Molecular Weight: 648.987
• Mol File: 873932-12-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: NiBr₂(P(C₆H₅)2C₆H₄CCH₃NC₉H₆N)(CAS DataBase Reference)
• NIST Chemistry Reference: NiBr₂(P(C₆H₅)2C₆H₄CCH₃NC₉H₆N)(873932-12-8)
• EPA Substance Registry System: NiBr₂(P(C₆H₅)2C₆H₄CCH₃NC₉H₆N)(873932-12-8)

Safety Data

• Hazardous Substances Data: 873932-12-8(Hazardous Substances Data)

Upstream product

• 28923-39-9 nickel(II) bromide dimethoxyethane 
• 578-66-5 8-amino quinoline 
• 50777-63-4 1-(2-(diphenylphosphanyl)phenyl)ethan-1-one 

Relevant articles and documents

Synthesis and characterization of tridentate nickel complexes bearing P∧N∧N and P∧N∧P ligands and their catalytic property in ethylene oligomerization

A series of nickel(II) complexes ligated by the N-(1-(2-(diarylphosphino) phenyl)methylidene)quinolin-8-amines (P∧N∧N) and 2-(diphenylphosphino)- N-[2-(diarylphosphino)benzylidene]anilines (P∧N∧P) were synthesized and characterized by elemental analysis, spectroscopy, and X-ray crystallography. X-ray crystallographic analyses reveal complexes 16 and 20 as having a five-coordinated distorted trigonal-bipyramidal geometry, while complex 12 displays a distorted square-pyramidal geometry and complex 13 is distorted square planar. Upon activation with MAO and AlEtCl2, these complexes exhibited considerably high activity (up to 1.34 × 106 g·mol-1(Ni)·h-1) of ethylene oligomerization. It was found that ligand environment and reaction conditions significantly affect the activity of the catalysts. In addition, a cobalt analogue with a distorted tetrahedral coordination geometry was investigated, which showed low activity of ethylene oligomerization.