874219-46-2

Basic information

• Product Name: 4-Chloro-3-(ethoxycarbonyl)phenylboronic acid
• Synonyms: ETHYL 5-BORONO-2-CHLOROBENZOATE;4-CHLORO-3-(ETHOXYCARBONYL)BENZENEBORONIC ACID;4-CHLORO-3-(ETHOXYCARBONYL)PHENYLBORONIC ACID;4-Chloro-3-(ethoxycarbonyl)benzeneboronic acid 96%;4-Chloro-3-(ethoxycarbony)phenylboronic acid;4-Chloro-3-(ethoxycarbonyl)benzeneboronicacid96%;(4-Chloro-3-(ethoxycarbonyl);4-Chloro-3-(ethoxycarbonyl)benzeneboronic
• CAS NO: 874219-46-2
• Molecular Formula: C₉H₁₀BClO₄
• Molecular Weight: 228.44
• Product Categories: blocks;BoronicAcids;Carboxes
• Mol File: 874219-46-2.mol
• Article Data: 1

Chemical Properties

• Melting Point: 162-164
• Boiling Point: 392.5 °C at 760 mmHg
• Flash Point: 191.2 °C
• Appearance: /
• Density: 1.33 g/cm³
• Vapor Pressure: 7.26E-07mmHg at 25°C
• Refractive Index: 1.543
• Storage Temp.: Keep Cold
• CAS DataBase Reference: 4-Chloro-3-(ethoxycarbonyl)phenylboronic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Chloro-3-(ethoxycarbonyl)phenylboronic acid(874219-46-2)
• EPA Substance Registry System: 4-Chloro-3-(ethoxycarbonyl)phenylboronic acid(874219-46-2)

Safety Data

• Hazard Codes: Xi
• Hazardous Substances Data: 874219-46-2(Hazardous Substances Data)

Usage

Uses

suzuki reaction

InChI:InChI=1/C9H10BClO4/c1-2-15-9(12)7-5-6(10(13)14)3-4-8(7)11/h3-5,13-14H,2H2,1H3

Upstream product

• 885067-50-5 ethyl 2-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate 
• 76008-73-6 5-Bromo-2-chloro-benzoic acid ethyl ester 

Downstream Products

• 1510865-82-3 tert-butyl 3-(4-chloro-3-(ethoxycarbonyl)phenyl)azetidine-1-carboxylate 

Relevant articles and documents

Metal-free coupling of saturated heterocyclic sulfonylhydrazones with boronic acids

The coupling of aromatic moieties with saturated heterocyclic partners is currently an area of significant interest for the pharmaceutical industry. Herein, we present a procedure for the metal-free coupling of 4-, 5-, and 6-membered saturated heterocyclic p-methoxyphenyl (PMP) sulfonylhydrazones with aryl and heteroaromatic boronic acids. This procedure enables a simple, two-step synthesis of a range of functionalized sp2-sp3 linked bicyclic building blocks, including oxetanes, piperidines, and azetidines, from their parent ketones.