874394-52-2Relevant articles and documents
A new synthesis of allyl sulfoxides via nucleophilic addition of sulfinyl carbanions to group 6 fischer carbene complexes
Barluenga, Jose,Fananas-Mastral, Martin,Aznar, Fernando
, p. 1235 - 1237 (2005)
(Chemical Equation Presented) A novel synthesis of allyl sulfoxides has been developed. Primary α-lithiosulfinyl carbanions react with group 6 Fischer carbene complexes to give allyl sulfoxides as products. The Fischer carbene complex experiments involve a 1,2-addition of two molecules of sulfinyl carbanion to give an intermediate that, after a β-elimination, furnishes the mentioned product.