87461-70-9

Basic information

• Product Name: Butanoic acid, heptafluoro-, (2,5-dimethoxy-4-methylphenyl)methyl ester
• CAS NO: 87461-70-9
• Molecular Formula: C14H13F7O4
• Molecular Weight: 378.244
• Mol File: 87461-70-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Butanoic acid, heptafluoro-, (2,5-dimethoxy-4-methylphenyl)methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Butanoic acid, heptafluoro-, (2,5-dimethoxy-4-methylphenyl)methyl ester(87461-70-9)
• EPA Substance Registry System: Butanoic acid, heptafluoro-, (2,5-dimethoxy-4-methylphenyl)methyl ester(87461-70-9)

Safety Data

• Hazardous Substances Data: 87461-70-9(Hazardous Substances Data)

Upstream product

• 336-64-1 bis(heptafluorobutyryl) peroxide 
• 2674-32-0 1,4-dimethoxy-2,5-dimethylbenzene 

Relevant articles and documents

Electron-Transfer Reactions between Perfluoroacyl Peroxides and Methoxybenzenes

(C3F7COO)2 and (C7F15COO)2 react rapidly with p-methoxytoluene and several p-dimethoxybenzenes in CCl2FCClF2 at 0 deg C.With p-dimethoxybenzene kinetics are first order in each component.High yields of ring-substituted products are obtained except for 2,5-dimethyl-1,4-dimethoxybenzene, 5, which gives the substituted benzyl perfluoroacyl ester.Rates and products are consistent with a rate-determining electron transfer, followed by product-forming reactions between the resulting radical cation-radical anion pairs.This is further supported by the formation of a perfluoroalkyl-substituted product from p-methoxytoluene and CIDNP emission from one system, indicating the presence of transient radical intermediates, although no free radicals were detected by scavenging experiments.