874635-67-3

Basic information

• Product Name: Benzonitrile, 4-[[2-[(hydroxyimino)methyl]phenyl]amino]-
• CAS NO: 874635-67-3
• Molecular Formula: C14H11N3O
• Molecular Weight: 237.261
• Mol File: 874635-67-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzonitrile, 4-[[2-[(hydroxyimino)methyl]phenyl]amino]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzonitrile, 4-[[2-[(hydroxyimino)methyl]phenyl]amino]-(874635-67-3)
• EPA Substance Registry System: Benzonitrile, 4-[[2-[(hydroxyimino)methyl]phenyl]amino]-(874635-67-3)

Safety Data

• Hazardous Substances Data: 874635-67-3(Hazardous Substances Data)

Upstream product

• 874635-65-1 4-(2-formylanilino)benzonitrile 

Downstream Products

• 874635-71-9 1-(4-cyanophenyl)-2-phenyl-1,2-dihydroquinazolin-3-ium-3-olate 

Relevant articles and documents

Bridgehead nitrogen heterocycles which contain the quinazoline moiety - Synthesis and cycloaddition of 1,2-dihydroquinazoline 3-oxides

A novel synthesis of 1,2-disubstituted 1,2-dihydroquinazoline 3-oxides 8 and the first ever examples of 1,3-dipolar trapping of these nitrones to homonuclear dipolarophiles is described. The new dipoles 8 reacted with N-methyl maleimide, generating diastereomeric adducts 14-16. In the reaction between 8 and dimethyl acetylenedicarboxylate, primary cycloadducts 17 and/or stable rearrangement products, azomethine ylides 18, are formed depending on the substitution pattern of the dipole. The structure of 18c is unambiguously assigned by X-ray crystallographic analysis. An X-ray crystal structure determination is also presented for the cyclopropylisoxazoloquinazoline 22 formed by a [3 + 2] addition of 8a to 21, the dimethyl acetylenedicarboxylate tetramer. The Royal Society of Chemistry 2005.