874955-58-5

Basic information

• Product Name: Cyclohexanol, 2-bromo-, (1R,2S)-
• CAS NO: 874955-58-5
• Molecular Formula: C6H11BrO
• Molecular Weight: 179.057
• Mol File: 874955-58-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 2-bromo-, (1R,2S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 2-bromo-, (1R,2S)-(874955-58-5)
• EPA Substance Registry System: Cyclohexanol, 2-bromo-, (1R,2S)-(874955-58-5)

Safety Data

• Hazardous Substances Data: 874955-58-5(Hazardous Substances Data)

Upstream product

• 1056477-06-5 2-bromocyclohexanone 
• 108-94-1 cyclohexanone 
• 5837-71-8 C₈H₁₃BrO₂ 
• 2425-33-4 cis-2-bromocyclohexanol 

Relevant articles and documents

Enzymatic preparation of (1S,2R)- and (1R,2S)-stereoisomers of 2-halocycloalkanols

The stereoisomers of cis-2-halocycloalkanols were resolved by a kinetically controlled transesterification with vinyl acetate in the presence of lipases in organic media. High enantioselectivities (ee >98%) and good isolated yields were obtained for all substrates using the appropriate lipase. Burkholderia cepacia lipase was the most efficient enzyme for the resolution of these substrates. The enantiomeric purities of the compounds were defined by derivatization with Mosher's acid and the absolute configurations were determined by chemical correlation.

Organocatalytic asymmetric α-bromination of aldehydes and ketones

The first organocatalytic enantioselective α-bromination of aldehydes and ketones is presented; a C2-symmetric diphenylpyrrolidine catalyst afforded the α-brominated aldehydes in good yields and up to 96% ee, while ketones were α-brominated by