87505-60-0Relevant articles and documents
The Use of 1-Phenylthioprop-1-yne as an Equivalent of Phenylthiopropanone in Aldol Condensations
Bridges, Alexander J.,Thomas, Ralph D.
, p. 485 - 486 (2007/10/02)
Addition of 1-lithio-1-phenylthiopropa-1,2-diene (7) to ketones, followed by trifluoroacetylation, a 3,3-rearrangement, and methanolysis of the resulting dienol trifluoroacetates, leads to the C-3 homologated α-phenylthioenones (2a) in 31-66percent overal