875118-61-9

Basic information

• Product Name: methyl 4-(((benzyloxy)carbonyl)amino)benzoate
• Synonyms: methyl 4-(((benzyloxy)carbonyl)amino)benzoate
• CAS NO: 875118-61-9
• Molecular Weight: 285.299
• Mol File: 875118-61-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 4-(((benzyloxy)carbonyl)amino)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-(((benzyloxy)carbonyl)amino)benzoate(875118-61-9)
• EPA Substance Registry System: methyl 4-(((benzyloxy)carbonyl)amino)benzoate(875118-61-9)

Safety Data

• Hazardous Substances Data: 875118-61-9(Hazardous Substances Data)

Upstream product

• 501-53-1 benzyl chloroformate 
• 619-45-4 4-methoxycarbonyl aniline 
• 621-84-1 O-benzyl carbamate 
• 619-42-1 4-methoxycarbonylphenyl bromide 

Downstream Products

• 619-45-4 4-methoxycarbonyl aniline 
• 1321594-60-8 C₂₆H₂₃N₃O₅S 
• 1321594-61-9 C₁₇H₁₇N₅O₂S 
• 1067891-53-5 methyl 4-((benzyloxycarbonyl)((2-methyloxiran-2-yl)methyl)amino)benzoate 

Relevant articles and documents

N-Arylation of Carbamates through Photosensitized Nickel Catalysis

A highly efficient method of visible light mediated Ni(II)-catalyzed photoredox N-arylation of Cbz-amines/Boc-amines with aryl electrophiles at room temperature is reported. The methodology provides a common access to a wide variety of N-aromatic and N-heteroaromatic carbamate products that find use in the synthesis of several biologically active molecules and provides a distinct advantage over traditional palladium-catalyzed Buchwald reaction.

Titanocene(III)-catalyzed formation of indolines and azaindolines

(Chemical Equation Presented) Reductive cyclization of epoxides tethered to substituted anilines and aminopyridines in the presence of 3 mol % of titanocene dichloride and stoichiometric manganese metal promotes a radical annulation to form 3,3-disubstituted indolines and azaindolines.