875431-05-3

Basic information

• Product Name: Ethanone, 1-[(4S,5R)-5-butyl-2-phenyl-1,3-dioxolan-4-yl]-
• CAS NO: 875431-05-3
• Molecular Formula: C15H20O3
• Molecular Weight: 248.322
• Mol File: 875431-05-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[(4S,5R)-5-butyl-2-phenyl-1,3-dioxolan-4-yl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[(4S,5R)-5-butyl-2-phenyl-1,3-dioxolan-4-yl]-(875431-05-3)
• EPA Substance Registry System: Ethanone, 1-[(4S,5R)-5-butyl-2-phenyl-1,3-dioxolan-4-yl]-(875431-05-3)

Safety Data

• Hazardous Substances Data: 875431-05-3(Hazardous Substances Data)

Upstream product

• 18402-82-9 (3E)-oct-3-en-2-one 
• 875431-00-8 (3S,4R)-3,4-dihydroxy-2-octanone 
• 1125-88-8 benzaldehyde dimethyl acetal 

Relevant articles and documents

A novel strategy for the convergent synthesis of 1,3,5,...-polyols: Enone formation, asymmetric dihydroxylation, reductive cleavage, hydride addition

Asymmetric dihydroxylation of α,β-unsaturated ketones provided α,β-dihydroxyketones with up to 100% ee. The Cα-O bond of these intermediates or their bis-TMS ethers, acetonides, phenylborates or orthoformiates was cleaved with SmI2, affording β-hydroxyketones. The latter can be reduced to furnish syn- or anti-configured 1,3-diols of any desired configuration. Georg Thieme Verlag Stuttgart.