875796-50-2Relevant articles and documents
Chiral recognition with silicon-stereogenic silanes: Remarkable selectivity factors in the kinetic resolution of donor-functionalized alcohols
Klare, Hendrik F. T.,Oestreich, Martin
, p. 9335 - 9338 (2008/12/21)
(Chemical Equation Presented) Slick silicon: A low-molecular-weight silane (C13H20Si, 204.38 g mol-1) with silicon-centered chirality is capable of discriminating enantiomeric rhodium-substrate complexes in dehydrogenative Si-O coupling reactions with outstanding selectivity factors (see scheme, s = selectivity factor).