875852-83-8Relevant articles and documents
Selectivity Relationships and Substituent-Substituent Interactions in Carbocation-Forming Bromination. The Transition-State Contribution to the ρ Variation
Ruasse, Marie-Francoise,Argile, Alain,Dubois, Jacques-Emile
, p. 4846 - 4849 (1984)
For arylolefin bromination through benzylic carbocations, X-C6H4-C+(R)-CHBr-R', there are 18 reaction constants, ρR, describing ring-substituent effect X, which vary from -1.6 to -5.9 depending on R and R' (H, Me, OMe, or Ar').This r