87587-65-3

Basic information

• Product Name: Diazene, bis(3,4-dimethoxyphenyl)-, 1-oxide
• CAS NO: 87587-65-3
• Molecular Formula: C16H18N2O5
• Molecular Weight: 318.329
• Mol File: 87587-65-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Diazene, bis(3,4-dimethoxyphenyl)-, 1-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: Diazene, bis(3,4-dimethoxyphenyl)-, 1-oxide(87587-65-3)
• EPA Substance Registry System: Diazene, bis(3,4-dimethoxyphenyl)-, 1-oxide(87587-65-3)

Safety Data

• Hazardous Substances Data: 87587-65-3(Hazardous Substances Data)

Upstream product

• 709-09-1 3,4-dimethoxynitrobenzene 
• 618-36-0 rac-methylbenzylamine 
• 6315-89-5 3,4-dimethoxyaniline 
• 75-31-0 isopropylamine 
• 87587-64-2 1,2-dimethoxy-4-nitrosobenzene 

Downstream Products

• 31237-07-7 bis-(3,4-dimethoxy-phenyl)-diazene 

Relevant articles and documents

Photosubstitution-photoreduction mechanistic duality in the SET photoreactions of nitrophenyl ethers with amines. The role of the steps that follow the ET

Nitrophenyl ethers are photoreduced by primary amines in water through a mechanism initiated by single electron transfer that is in direct competition with the single electron transfer photosubstitution mechanism (S(N)Ar*-SET). Our results indicate that the preferred pathway does not depend on the electron donor or proton donor ability of the amine. The key factor that determines the progress of the photoreaction is the structure of the carbon skeleton of the amine, particularly the type of hydrogens on the carbon α to the amino group. A mechanistic rationale that includes hydrogen atom transfer as a key step is discussed.

Solid state photochemistry of ternary cyclodextrin complexes: Total selectivity in the photoreduction of nitrophenyl ethers by 1-phenylethylamine

The irradiation of the ternary complexes of β-cyclodextrin with several nitrophenyl ethers, and 1-phenylethylamine in the solid state, produces selective photoreduction to the corresponding nitroso derivatives.