87611-61-8

Basic information

• Product Name: (Z)-5-Hydroxy-dec-7-enoic acid
• CAS NO: 87611-61-8
• Molecular Weight: 186.251
• Mol File: 87611-61-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-5-Hydroxy-dec-7-enoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-5-Hydroxy-dec-7-enoic acid(87611-61-8)
• EPA Substance Registry System: (Z)-5-Hydroxy-dec-7-enoic acid(87611-61-8)

Safety Data

• Hazardous Substances Data: 87611-61-8(Hazardous Substances Data)

Upstream product

• 42537-02-0 2-<(Z)-2-pentenyl>cyclopentanone 

Downstream Products

• 25524-95-2 Jasmin lactone 

Relevant articles and documents

BAEYER-VILLIGER OXIDATION WITH Me3SiOOSiMe3 UNDER ASSISTANCE OF SnCl4 OR BF3-OEt2.

Treatment of ketones with bis(trimethylsilyl) peroxide and Lewis acid such as SnCl//4 or BF//3-OEt//2 in dichloromethane at room temperature affords esters in fair to excellent yields. Jasmine lactone is synthesized from 2- left bracket (Z)-pentenyl right bracket cyclopentanine by means of Me//3SiOOSiMe//3-BF//3-OEt//2 system without any protection of the carbon-carbon double bond. The oxidation of enol acetates of ketones to alpha -hydroxy (or alpha -acetoxy) ketones with Me//3SiOOSiMe//3-FeCl//3 system is also disclosed.