87657-60-1

Basic information

• Product Name: (2S-trans)-N-<2-methyl-4-oxo-3-azetidinyl>-2-phenoxyacetamide
• Synonyms: (2S-trans)-N-<2-methyl-4-oxo-3-azetidinyl>-2-phenoxyacetamide
• CAS NO: 87657-60-1
• Molecular Weight: 234.255
• Mol File: 87657-60-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2S-trans)-N-<2-methyl-4-oxo-3-azetidinyl>-2-phenoxyacetamide(CAS DataBase Reference)
• NIST Chemistry Reference: (2S-trans)-N-<2-methyl-4-oxo-3-azetidinyl>-2-phenoxyacetamide(87657-60-1)
• EPA Substance Registry System: (2S-trans)-N-<2-methyl-4-oxo-3-azetidinyl>-2-phenoxyacetamide(87657-60-1)

Safety Data

• Hazardous Substances Data: 87657-60-1(Hazardous Substances Data)

Upstream product

• 133815-39-1 N-[(2S,3R)-2-Benzenesulfonyl-1-(tert-butyl-dimethyl-silanyl)-2-methyl-4-oxo-azetidin-3-yl]-2-phenoxy-acetamide 
• 133789-00-1 N-[(2S,3R)-2-Benzenesulfonyl-1-(tert-butyl-dimethyl-silanyl)-4-oxo-azetidin-3-yl]-2-phenoxy-acetamide 
• 88002-47-5 (3R-trans)-3-phenoxyacetylamino-4-phenylsulfonyl-2-azetidinone 
• 35592-67-7 (3S,4S)-4-acetoxy-3-phenoxyacetamido-azetidin-2-one 
• 87791-62-6 (3S,4S)-3-amino-4-methyl-azetidin-2-one 
• 701-99-5 Phenoxyacetyl chloride 
• 917-54-4 methyllithium 

Relevant articles and documents

Stereoselective Synthesis of Cis-Substituted Azetidinones from Penicillin: a Formal Total Synthesis of Loracarbef

A new method for the synthesis of chiral azetidinones bearing a carbon-carbon bond at the 4-position is described.The preparation involves a stereoselective alkylation-reduction of a silylated 4-phenylsulfonyl azetidinone.The utility of this method was demonstrated by a formal total synthesis of loracarbef.

STUDIES ON THE REACTIVITY OF 4-ACETOXY-3-ACYLAMINO-2-AZETIDINONES: STEREOSPECIFIC trans CARBON-CARBON BOND FORMATION

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