87664-38-8Relevant articles and documents
PHOSPHINES SULFONEES ASYMETRIQUES V. CINETIQUE DE SULFONATION DES PHOSPHINES
Lecomte, L.,Sinou, D.
, p. 239 - 251 (2007/10/02)
The sulfonation of 1,2-, 1,3- and 1,4-diphosphines (dppe, dppp, dppb) is studied.It is shown that the sulfonation is faster for 1,4-diphophines than for 1,3- and 1,2-diphosphines.The conditions affording the tetrasulfonation are described, and also those allowing the obtention of a mixture containing large amounts of disulfonated diphosphines.This study is extended to chiral diphosphines (Cyclobutanediop, BDPP, Chiraphos).