87712-70-7Relevant articles and documents
Gas-phase reactions of the hydroperoxide and performate anions
Bowie, John H.,DePuy, Charles H.,Sullivan, Sally A.,Bierbaum, Veronica M.
, p. 1046 - 1050 (1986)
The flowing afterglow technique has been used to study the reactions of HO2- and HCO3- in the gas phase.The hydroperoxide ion reacts slowly with CO to form HO-, and oxidizes CO2, OCS, CS2, NO, SO2, CH3NCS in fast reactions to form CO3-, CO2S-, COS2-, NO2-, SO3-, CH3NCO2-, and CH3NCOS-, respectively.Reactions of HO2- with certain amides and esters provide synthetic routes for a number of interesting peracyl anions.One of these, the peroxyformate ion, HCO3-, reacts with CO and NO in slow oxidation reactions to form the formate ion HCO2-.It also forms HCO2- upon reaction with acetone and pivalaldehyde, perhaps by Baeyer-Villiger oxidation.