87743-15-5Relevant articles and documents
A convenient synthetic route to 2,4,6-tris(chlorosulfonyl)- and 2,4,6-tris(fluorosulfonyl)phenol, aniline and chlorobenzene
Boiko, Vladimir N.,Filatov, Andrey A.,Yagupolskii, Yurii L.,Tyrra, Wieland,Naumann, Dieter,Pantenburg, Ingo,Fischer, Hendrik T.M.,Schulz, Frank
experimental part, p. 1219 - 1226 (2011/11/30)
Convenient and preparative synthetic procedures of 2,4,6- tris(chlorosulfonyl)- and 2,4,6-tris(fluorosulfonyl)phenol, -chlorobenzene and -aniline have been elaborated. Chlorine exchange for fluorine by KF interaction on 2,4,6-tris(chlorosulfonyl)aniline and especially 2,4,6-tris(chlorosulfonyl) phenol proceeds easily and selectively under anhydrous conditions in dioxane. Unlike, 2,4,6-tris(chlorosulfonyl)chlorobenzene transformation requires the presence of water. On the basis of 2,4,6-tris(fluorosulfonyl)phenol and some of its salts, XRD measurements demonstrated the structural similarity to picric acid and its derivatives in the solid state.
ANILINE-2,4,6-TRISULPHONYLCHLORIDE AND DARIVED SULPHONAMIDES
Booth,Gerald
, p. 659 - 662 (2007/10/02)
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