87751-69-7

Basic information

• Product Name: (±)-trans-1,3-Diphenylallyl acetate
• Synonyms: (±)-trans-1,3-Diphenylallyl acetate;(+/-)-trans-1,3-Diphenylallyl acetate 97%;Acetic acid trans-1,3-diphenylallyl ester
• CAS NO: 87751-69-7
• Molecular Formula: C₁₇H₁₆O₂
• Molecular Weight: 252.30774
• Mol File: 87751-69-7.mol
• Article Data: 28

Chemical Properties

• Appearance: /
• BRN: 3610772
• CAS DataBase Reference: (±)-trans-1,3-Diphenylallyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (±)-trans-1,3-Diphenylallyl acetate(87751-69-7)
• EPA Substance Registry System: (±)-trans-1,3-Diphenylallyl acetate(87751-69-7)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 87751-69-7(Hazardous Substances Data)

Usage

Description

(±)-trans-1,3-Diphenylallyl acetate is a chiral chemical compound with the molecular formula C18H16O2. It belongs to the class of allyl acetates, characterized by a double bond between carbon atoms. (±)-trans-1,3-Diphenylallyl acetate is known for its unique structure and reactivity, making it a versatile building block in the synthesis of various organic compounds, including pharmaceuticals, fragrances, and specialty chemicals. Its dual mirror-image forms add to its complexity and applicability in different fields.

Uses

Used in Organic Synthesis:
(±)-trans-1,3-Diphenylallyl acetate is utilized as a key starting material in organic synthesis for the production of a wide range of organic compounds. Its reactivity and structural features make it a valuable component in creating pharmaceuticals, fragrances, and specialty chemicals.
Used in Pharmaceutical Industry:
In the pharmaceutical sector, (±)-trans-1,3-Diphenylallyl acetate serves as an essential intermediate in the synthesis of various drugs. Its unique properties allow for the development of new medicinal compounds with potential therapeutic applications.
Used in Fragrance Industry:
(±)-trans-1,3-Diphenylallyl acetate is employed as a building block for creating unique fragrances and scents. Its chemical structure contributes to the development of novel aroma compounds used in perfumes, cosmetics, and other scented products.
Used in Food and Beverage Industry:
As a flavoring agent and aroma compound, (±)-trans-1,3-Diphenylallyl acetate plays a significant role in enhancing the taste and smell of various food and beverage products. Its incorporation into these products contributes to their overall sensory appeal.
Used in Scientific Research:
(±)-trans-1,3-Diphenylallyl acetate is also an important compound in scientific research, where it is studied for its properties and potential applications in various chemical and biological processes. Researchers explore its reactivity and behavior in different reaction conditions to gain insights into its potential uses and mechanisms.

Upstream product

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• 98-80-6 phenylboronic acid 
• 591-50-4 iodobenzene 
• 64847-78-5 (E)-1,1-diacetoxy-3-phenylprop-2-ene 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 4663-33-6 1,3-diphenyl-3-hydroxypropene 
• 62668-02-4 (E)-1,3-diphenyl-2-propen-1-ol 

Downstream Products

• 121440-78-6 (E)-N-(1,3-diphenyl-1λ³-allyl)-4-methylbenzenesulfonamide 
• 171927-27-8 3-[(2E)-1,3-diphenylprop-2-en-1-yl]-pentane-2,4-dione 
• 863225-69-8 (S)-N,N-diformyl-1,3-diphenylprop-2-en-1-ylamide 
• 297179-04-5 (R)-3-acetoxy-1,3-diphenyl-1-propene 
• 354816-61-8 (S)-3-acetoxy-1,3-diphenyl-1-propene 
• 204578-86-9 ((1E,5E)-hexa-1,5-diene-1,3,4,6-tetrayl)tetrabenzene 
• 177468-91-6 (E)-dimethyl (1,3-diphenylprop-2-en-1-yl)propanedioate 
• 95071-02-6 dimethyl 2-[(E)-(S)-1,3-diphenylallyl]-malonate 

Relevant articles and documents

Pd-Catalyzed Nazarov-Type Cyclization: Application in the Total Synthesis of β-Diasarone and Other Complex Cyclopentanoids

We describe the palladium-catalyzed Nazarov-type cyclization of easily accessible (hetero)arylallyl acetates to pentannulated (hetero)arenes. This method provides ready access to various types of bi-, tri-, tetra-, and pentacyclic cyclopentanoids under ne

METHODS AND COMPOSITIONS FOR SUBSTITUTED ARYLCYCLOHEPTANE ANALOGS

In one aspect, the disclosure relates to methods for preparation of intermediates useful for the preparation of aryl-cycloheptene scaffolds. In a further aspect, the disclosed methods pertain to the preparation of compounds comprising an aryl-cycloheptene

Pd/BIPHEPHOS is an Efficient Catalyst for the Pd-Catalyzed S-Allylation of Thiols with High n-Selectivity

The Pd-catalyzed S-allylation of thiols with stable allylcarbonate and allylacetate reagents offers several advantages over established reactions for the formation of thioethers. We could demonstrate that Pd/BIPHEPHOS is a catalyst system which allows the transition metal-catalyzed S-allylation of thiols with excellent n-regioselectivity. Mechanistic studies showed that this reaction is reversible under the applied reaction conditions. The excellent functional group tolerance of this transformation was demonstrated with a broad variety of thiol nucleophiles (18 examples) and allyl substrates (9 examples), and could even be applied for the late-stage diversification of cephalosporins, which might find application in the synthesis of new antibiotics. (Figure presented.).