877869-48-2

Basic information

• Product Name: 1-Propanone, 2-[(4-methoxyphenyl)methoxy]-1-phenyl-
• CAS NO: 877869-48-2
• Molecular Formula: C17H18O3
• Molecular Weight: 270.328
• Mol File: 877869-48-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 2-[(4-methoxyphenyl)methoxy]-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 2-[(4-methoxyphenyl)methoxy]-1-phenyl-(877869-48-2)
• EPA Substance Registry System: 1-Propanone, 2-[(4-methoxyphenyl)methoxy]-1-phenyl-(877869-48-2)

Safety Data

• Hazardous Substances Data: 877869-48-2(Hazardous Substances Data)

Upstream product

• 100-59-4 phenylmagnesium chloride 
• 865620-61-7 methyl 2-(4-methoxybenzyloxy)propionate 
• 5650-40-8 2-hydroxypropiophenone 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 

Downstream Products

• 877869-51-7 (Z)-methyl 4-(p-methoxyphenyl)methoxy-2-methyl-3-phenyl-2-pentenoate 

Relevant articles and documents

Synthesis of Highly Substituted Furans by a Cascade of Formal anti-Carbopalladation/Hydroxylation and Elimination

Highly substituted furans are generated by a cascade of formal anti-carbopalladation, attack of a nucleophilic hydroxy group, and aromatization by elimination of the emerging dihydrofuran derivative. Mono-, di-, and trisubstituted furans were obtained in good to excellent yields. When we attempted to access tetrasubstituted furan derivatives, an additional rearrangement was observed that resulted in the formation of chromenes. Follow-up chemistry shows the utility of TMS as a protecting group for the alkyne moiety.