87826-20-8

Basic information

• Product Name: FeC₅H₅(CH(CH₃)(C₆H₁₁)2N)C₅H₄
• CAS NO: 87826-20-8
• Molecular Weight: 393.396
• Mol File: 87826-20-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: FeC₅H₅(CH(CH₃)(C₆H₁₁)2N)C₅H₄(CAS DataBase Reference)
• NIST Chemistry Reference: FeC₅H₅(CH(CH₃)(C₆H₁₁)2N)C₅H₄(87826-20-8)
• EPA Substance Registry System: FeC₅H₅(CH(CH₃)(C₆H₁₁)2N)C₅H₄(87826-20-8)

Safety Data

• Hazardous Substances Data: 87826-20-8(Hazardous Substances Data)

Upstream product

• 1277-49-2 1-ferrocenylethanol 
• 101-83-7 N-cyclohexyl-cyclohexanamine 

Relevant articles and documents

The synthesis of primary, secondary, and tertiary ferrocenylethylamines

A simplified procedure for the preparation of α-N,N-dialkylaminoethylferrocenes R2NR' (r=Me, C6H11, CHMe2; R'=CH(CH3)C5H4FeC5H5) from the alcohol R'OH by treatment with HBr and R2NH is described.Use of ammonia results in the isolation of R'NH2, R'2NH (major product) and R'3N and use of the optically active amine d-(+)-H2NCH(CH3)C6H5 gives rise to diastereomers R'NHCH(CH3)C6H5 which are separable.When diphenylphosphine is substituted for an amine the oxide R'P(O)Ph2 is obtained in low yield.The secondary amine R'2NH reacts with n-butyllithium and chlorodiphenylphosphine to afford R'2NHPPh2.