87925-40-4Relevant articles and documents
Syntheses with Nitriles, LXIX. Isomeric Diamino Alkoxy Pyridine Carbonitriles-Separation and Application as Coupling Components
Junek, Hans,Uray, Georg,Kotzent, Anna
, p. 973 - 982 (2007/10/02)
The isomeric 4,6-diamino-2-alkoxy- (3), and 2,4-diamino-6-alkoxy-3-pyridine-carbonitriles (4) are obtained by treatment of 2-amino-1,1,3-tricyanopropene (1) with sodium alkoxides.Separation is based on their different pKα-values (3a = 2.01, 4a = 4.17).Coupling reaction of 3a-c with benzenediazonium chloride in strong acidic medium leads to the yellow azo dyes 5a-c, whereas coupling of 4a requires a buffered solution (pH 4-6) to yield 6.The UV-VIS spectra of the isomer pyridines and the azo dyes are discussed. - keywords: Azo Dyes; Diamino-alkoxy-pyridine-carbonitriles; UV-VIS spectra