87931-16-6

Basic information

• Product Name: 1,3-Diisopropyl-2-(3-methoxy-phenyl)-isourea; compound with picric acid
• CAS NO: 87931-16-6
• Molecular Weight: 479.447
• Mol File: 87931-16-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-Diisopropyl-2-(3-methoxy-phenyl)-isourea; compound with picric acid(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Diisopropyl-2-(3-methoxy-phenyl)-isourea; compound with picric acid(87931-16-6)
• EPA Substance Registry System: 1,3-Diisopropyl-2-(3-methoxy-phenyl)-isourea; compound with picric acid(87931-16-6)

Safety Data

• Hazardous Substances Data: 87931-16-6(Hazardous Substances Data)

Upstream product

• 150-19-6 O-methylresorcine 
• 88-89-1 2,4,6-Trinitrophenol 
• 693-13-0 diisopropyl-carbodiimide 

Relevant articles and documents

Degradation of O-Arylisoureas in Alkali: A Low-temperature Chapman-type Rearrangement

NN'-Di-isopropyl-O-arylisoureas are demonstrated to rearrange intramolecularly to the corresponding NN'-di-isopropyl-N'-arylurea in alkaline solution.The large negative Broensted-type βL value (-2.3) for the reaction measured against the pK of the corresponding phenol and a modest entropy of activation are consistent with a 1,3-aryl migration.The high efficiency of the migration compared with that of the Chapman rearrangement of O-aryl imidoethers is attributed to the greater internal nucleophilicity of the imino nitrogen, which in the present case bears a negative charge.