87938-12-3

Basic information

• Product Name: Ethanehydrazonic acid, N-(1-methylethylidene)-, 2,2,2-trichloroethyl ester, (E)-
• CAS NO: 87938-12-3
• Molecular Formula: C7H11Cl3N2O
• Molecular Weight: 245.536
• Mol File: 87938-12-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanehydrazonic acid, N-(1-methylethylidene)-, 2,2,2-trichloroethyl ester, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanehydrazonic acid, N-(1-methylethylidene)-, 2,2,2-trichloroethyl ester, (E)-(87938-12-3)
• EPA Substance Registry System: Ethanehydrazonic acid, N-(1-methylethylidene)-, 2,2,2-trichloroethyl ester, (E)-(87938-12-3)

Safety Data

• Hazardous Substances Data: 87938-12-3(Hazardous Substances Data)

Upstream product

• 87938-01-0 2,2,5-Trimethyl-5-(2,2,2-trichloro-ethoxy)-2,5-dihydro-[1,3,4]oxadiazole 

Relevant articles and documents

Carbene Reactions with Cis Azo Functions. Formation of Ester Azines from Δ3-1,3,4-Oxadiazolines

Thermolysis of a 2-alkoxy-2,5,5-trialkyl-Δ3-1,3,4-oxadiazoline (1), either neat or in a solvent such as benzene, leads to a carbonyl ylide intermediate which fragments to carbonyl compounds and carbenes.The latter attack the parent oxadiazoline at the azo function, presumably to form azomethine imine ylides.The latter ylides then fragment to form carbonyl compounds and azines such as R1(R2O)C=NN=C(OR2)R1, R1(R2O)C=NN=C(R3)2 and (R3)2C=NN=C(R3)2.The mechanism proposed is supported by results of studies of the dependence of the azine and propeneyields on the initial oxadiazoline concentration.More propene and less (R3)2C=NN=C(R3)2 are obtained at low oxadiazoline concentrations, as would be expected if both arise from dimethyl carbene.