87959-49-7

Basic information

• Product Name: Benzene, 1-methoxy-4-(1-methyl-1,2-propadienyl)-
• CAS NO: 87959-49-7
• Molecular Formula: C11H12O
• Molecular Weight: 160.216
• Mol File: 87959-49-7.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-(1-methyl-1,2-propadienyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-(1-methyl-1,2-propadienyl)-(87959-49-7)
• EPA Substance Registry System: Benzene, 1-methoxy-4-(1-methyl-1,2-propadienyl)-(87959-49-7)

Safety Data

• Hazardous Substances Data: 87959-49-7(Hazardous Substances Data)

Upstream product

• 1712-69-2 1-isopropenyl-4-methoxybenzene 
• 52178-73-1 1-(2,2-dibromo-1-methylcyclopropyl)-4-methoxybenzene 
• 925-90-6 ethylmagnesium bromide 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 1132766-14-3 4-methoxyphenyldimethylaluminum 

Downstream Products

• 87959-54-4 1-(2,2-Dibromo-1-methyl-3-methylene-cyclopropyl)-4-methoxy-benzene 
• 87959-61-3 1-(2-Dibromomethylene-1-methyl-cyclopropyl)-4-methoxy-benzene 
• 235101-21-0 (R)-2-(4-methoxyphenyl)-2-methylbut-3-en-1-ol 

Relevant articles and documents

Construction of All-Carbon Chiral Quaternary Centers through CuI-Catalyzed Enantioselective Reductive Hydroxymethylation of 1,1-Disubstituted Allenes with CO2

A catalytic enantioselective construction of all-carbon chiral quaternary centers through reductive hydroxymethylation of 1,1-disubstituted allenes with CO2 has been developed. In the presence of a copper/Mandyphos catalyst, CO2 is t

A convenient access to allylic triflones with allenes and triflyl chloride in the presence of (EtO)2P(O)H

A simple method for the preparation of allylic triflones from allenes and triflyl chloride in the presence of (EtO)2P(O)H has been developed. The features of this reaction are catalyst-free and simple starting substrates. This method tolerates diverse functional groups and substituted allylic triflones are obtained in moderate to good yields.

Fluorinative Rearrangements of Substituted Phenylallenes Mediated by (Difluoroiodo)toluene: Synthesis of α-(Difluoromethyl)styrenes

Phenylallenes undergo fluorinative rearrangement upon the action of (difluoroiodo)toluene in the presence of 20 mol % BF3?OEt2 to yield α-difluoromethyl styrenes. This unprecedented reaction was entirely chemoselective for the internal allene π bond, and showed remarkable regioselectivity during the fluorination event. Substituted phenylallenes, phenylallenes possessing both phenyl- and α-allenyl substituents, and diphenylallenes were investigated, and good functional-group compatibility was observed throughout. The ease with which allenes can be prepared on a large scale, and the operational simplicity of this reaction allowed us to rapidly access fluorine-containing building blocks that have not been accessed by conventional deoxyfluorination strategies.