880550-63-0

Basic information

• Product Name: N-(7-bromo-2,2-dimethyl-2-silatetralin-6-yl)-N-methylveratramide
• CAS NO: 880550-63-0
• Molecular Weight: 448.432
• Mol File: 880550-63-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(7-bromo-2,2-dimethyl-2-silatetralin-6-yl)-N-methylveratramide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(7-bromo-2,2-dimethyl-2-silatetralin-6-yl)-N-methylveratramide(880550-63-0)
• EPA Substance Registry System: N-(7-bromo-2,2-dimethyl-2-silatetralin-6-yl)-N-methylveratramide(880550-63-0)

Safety Data

• Hazardous Substances Data: 880550-63-0(Hazardous Substances Data)

Upstream product

• 880550-60-7 6-amino-2,2-dimethyl-2-silatetralin 
• 880550-61-8 6-methylamino-2,2-dimethyl-2-silatetralin 
• 880550-58-3 1-(2,2-dimethyl-1,2,3,4-tetrahydro-benzo[c]silin-6-yl)-ethanone oxime 
• 880550-59-4 6-acetamino-2,2-dimethyl-2-silatetralin 
• 93-07-2 Veratric acid 
• 175730-69-5 6-acetyl-2,2-dimethyl-2-silatetralin 

Relevant articles and documents

Synthesis of N-methylphenanthridinone derivatives fused with a silacyclohexane ring by radical reaction using tributyltin hydride

Radical reaction of (N-methyl-7-bromo-2,2-dimethyl-2-silatetralin-6-ylamino)veratramide (8a) and -piperonamides (8b) in boiling benzene using tributyltin hydride and AIBN gave two kinds of N-methylphenanthridinone derivatives (15 and 16), which were cyclized at 6- and 2-positions of aroylic acid moiety. On the other hand, similar reaction of N-methyl-N-(2-bromoveratryl and 2-bromopiperonyl)-2,2-dimethyl-2-silatetralin-6-carboxamides (14) produced N-methylphenanthridinone deivatives (17) as each sole product, in which cyclization occurred at 5-position of 2-silatetralin moiety.