88073-36-3Relevant articles and documents
Stereoselective synthesis of α-ylidene-β-dicarbonyl compounds: A mild PhI(OAc)2-mediated dehydrogenation process
Fan, Liyan,Chen, Wen,Tang, Kunshan,Wu, Dongbei
, p. 940 - 942 (2012/11/06)
PhI(OAc)2-mediated dehydrogenation of α-alkyl-β-dicarbonyl compound has been developed to afford α-ylidene-β- dicarbonyl compounds with high stereoselectivity under mild conditions. This process provides a complementary entry to stereoselectivity for the Knoevenagel reaction.
Photosensitized Oxidation of Furans. Part 7. Solvent Effects in Thermal Conversion of the endo-Peroxides of Arylfurans
Graziano, M. Liliana,Iesce, M. Rosaria,Chiosi, Sergio,Scarpati, Rachele
, p. 2071 - 2074 (2007/10/02)
Thermal conversion of the endo-peroxides of the arylfurans (1) in a polar aprotic solvent leads to aroylenol esters (4) and diaroyl epoxides (3), the predominance of one over being concentration dependent.The results can be rationalized on the basis of th