88089-38-7

Basic information

• Product Name: (3aS,4S,9aR,9bR)-4-Benzoyl-2-methyl-3a,4,9a,9b-tetrahydro-pyrrolo[3,4-a]indolizine-1,3-dione
• Synonyms: (3aS,4S,9aR,9bR)-4-Benzoyl-2-methyl-3a,4,9a,9b-tetrahydro-pyrrolo[3,4-a]indolizine-1,3-dione
• CAS NO: 88089-38-7
• Molecular Weight: 308.337
• Mol File: 88089-38-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (3aS,4S,9aR,9bR)-4-Benzoyl-2-methyl-3a,4,9a,9b-tetrahydro-pyrrolo[3,4-a]indolizine-1,3-dione(CAS DataBase Reference)
• NIST Chemistry Reference: (3aS,4S,9aR,9bR)-4-Benzoyl-2-methyl-3a,4,9a,9b-tetrahydro-pyrrolo[3,4-a]indolizine-1,3-dione(88089-38-7)
• EPA Substance Registry System: (3aS,4S,9aR,9bR)-4-Benzoyl-2-methyl-3a,4,9a,9b-tetrahydro-pyrrolo[3,4-a]indolizine-1,3-dione(88089-38-7)

Safety Data

• Hazardous Substances Data: 88089-38-7(Hazardous Substances Data)

Upstream product

• 930-88-1 N-methylmaleimide 
• 36377-40-9 pyridinium benzoylmethylide 
• 16883-69-5 N-phenacylpyridinium bromide 

Downstream Products

• 118355-86-5 (1S,2aS,5aS,5bS,8aR,8bR)-1-Benzenesulfonyl-8b-benzoyl-7-methyl-1,2,2a,5,5a,5b,8a,8b-octahydro-7,8c-diaza-dicyclopenta[a,cd]indene-6,8-dione 
• 118355-85-4 (1R,2aR,5aR,5bR,8aS,8bS)-8b-Benzoyl-7-methyl-6,8-dioxo-2,2a,5,5a,5b,6,7,8,8a,8b-decahydro-1H-7,8c-diaza-dicyclopenta[a,cd]indene-1-carbonitrile 
• 90625-59-5 (E)-1-methyl-3-(2-oxo-2-phenylethylidene)pyrrolidine-2,5-dione 

Relevant articles and documents

Electrophilicities of 1,2-disubstituted ethylenes

The kinetics of the reactions of maleic anhydride, N-methylmaleimide, fumaronitrile, diethyl fumarate, and diethyl maleate with pyridinium and sulfonium ylides were studied in DMSO at 20 C. All of the reactions were found to follow a second-order rate law

Cycloaddition of Pyridinium Methylides with Electron-Deficient Olefins and Silica-Gel Mediated Elimination of Pyridines from the Cycloadducts: A New Method of Alkylation or Hydroalkylidenation of Olefins

Pyridinium methylides bearing an anion-stabilizing substituent at the ylide carbon react with a variety of olefins carrying two electron-withdrawing groups at the both carbons such as N-substituted maleimides, a citraconimide, dimethyl maleate, dimethyl f

STEREOSELECTIVE HYDROALKYLIDENATION OF OLEFIN WITH PYRIDINIUM METHYLIDES

Acid-catalyzed elimination of pyridine from the stereoselective cycloadducts between electron-deficient olefins and pyridinium methylides with ylide-stabilizing substituents offers a new type of C-C bond formation.