881073-98-9

Basic information

• Product Name: [(C6F5)2Pt(μ-PPh2)2PtI2]
• CAS NO: 881073-98-9
• Molecular Weight: 1348.46
• Mol File: 881073-98-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(C6F5)2Pt(μ-PPh2)2PtI2](CAS DataBase Reference)
• NIST Chemistry Reference: [(C6F5)2Pt(μ-PPh2)2PtI2](881073-98-9)
• EPA Substance Registry System: [(C6F5)2Pt(μ-PPh2)2PtI2](881073-98-9)

Safety Data

• Hazardous Substances Data: 881073-98-9(Hazardous Substances Data)

Upstream product

• 881073-95-6 [(C₆F₅)₂Pt(μ-PPh₂)₂Pt(CH₃CN)₂] 
• 7553-56-2 iodine 

Relevant articles and documents

Formation of PPh2C6F5 through phosphido platinum and/or palladium(III) intermediates

The two-electron oxidation reactions of the neutral [(C6F 5)2M(μ-PR2)2M′(NCCH 3)2 (M = M′ = Pt or Pd, M = Pt, M′ = Pd) complexes using I2 as oxidant have been investigated by experimental (R = Ph) and electronic structure calculation methods (R = H). It was found that a reductive coupling of PR2 and C6F5 takes place along the reaction pathway for all oxidized complexes. The most salient structural features of the [(C6F5)2Pt(μ- PR2)2Pd(C6F5)2] 2-, [(C6F5)2Pd(μ-PR 2)2Pd(acac)]-, and [(C6F 5)2Pt(μ-PR2)2PtI2] complexes (experimental R = Ph) are reproduced very well by the B3LYP/lanl2dz calculations (R = H).