88174-48-5

Basic information

• Product Name: Benzaldehyde, 2-ethoxy-4,6-dimethyl-
• Synonyms: Benzaldehyde,2-ethoxy-4,6-dimethyl
• CAS NO: 88174-48-5
• Molecular Formula: C11H14O2
• Molecular Weight: 178.22800
• Mol File: 88174-48-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 2-ethoxy-4,6-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 2-ethoxy-4,6-dimethyl-(88174-48-5)
• EPA Substance Registry System: Benzaldehyde, 2-ethoxy-4,6-dimethyl-(88174-48-5)

Safety Data

• Hazardous Substances Data: 88174-48-5(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 15764-16-6 2,4-dimethylbenzaldehyde 

Relevant articles and documents

Monodentate Transient Directing Group Enabled Pd-Catalyzed Ortho-C-H Methoxylation and Chlorination of Benzaldehydes

We report Pd-catalyzed ortho-C-H methoxylation and chlorination of benzaldehydes by employing monodentate transient directing groups (TDGs) as an alternative strategy to bidentate TDGs. More importantly, a single crystal of benzaldehyde imine ortho-cyclopalladium intermediate was successfully obtained, and its structure was unambiguously determined by X-ray diffraction, which clearly showed that it was a binuclear palladium species bridged by a pyridone ligand. The utility of this approach was further demonstrated through the synthesis of key intermediates of natural products and drugs.