88198-30-5

Basic information

• Product Name: (2R,6aβ,10bβ)-3α-Ethenyldodecahydro-3,4aα,7,7,10aα-pentamethyl-1H-naphtho[2,1-b]pyran-2β-ol
• Synonyms: (2R,6aβ,10bβ)-3α-Ethenyldodecahydro-3,4aα,7,7,10aα-pentamethyl-1H-naphtho[2,1-b]pyran-2β-ol;Varol
• CAS NO: 88198-30-5
• Molecular Formula: C20H34O2
• Molecular Weight: 306.48276
• Mol File: 88198-30-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (2R,6aβ,10bβ)-3α-Ethenyldodecahydro-3,4aα,7,7,10aα-pentamethyl-1H-naphtho[2,1-b]pyran-2β-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,6aβ,10bβ)-3α-Ethenyldodecahydro-3,4aα,7,7,10aα-pentamethyl-1H-naphtho[2,1-b]pyran-2β-ol(88198-30-5)
• EPA Substance Registry System: (2R,6aβ,10bβ)-3α-Ethenyldodecahydro-3,4aα,7,7,10aα-pentamethyl-1H-naphtho[2,1-b]pyran-2β-ol(88198-30-5)

Safety Data

• Hazardous Substances Data: 88198-30-5(Hazardous Substances Data)

Upstream product

• 1616-86-0 cis-abienol 

Downstream Products

• 122551-69-3 Acetic acid (2S,3R,4aR,6aS,10aS)-3,4a,7,7,10a-pentamethyl-3-vinyl-dodecahydro-benzo[f]chromen-2-yl ester 

Relevant articles and documents

Tobacco Chemistry 81. Biotransformations of (Z)-Abienol using Plant Cell Cultures of Nicotiana silvestris

The transformations of (Z)-abienol (1) effected by cell cultures and cell-free extracts of Nicotiana silvestris and by horseradish peroxidase have been examined.Although this compound retarded the growth of the cell cultures in low doses and exhibited a toxic effect in high doses, a fairly rapid conversion was observed when low to moderate doses of cells cultivated under light were used.Of the many transformation products encountered twelve were identified.The major ones of these were (12R,13S)- and (12R,13R)-8,12-epoxy-14-labden-13-ols (2,5), (11E)-14,15-bisnor-8-hydroxy-11-labden-13-one (11), 12-norambreinolide (10), 12,15-epoxy-12,14-labdadien-8-ol (12) and 8-drimanol (13), and the minor (12R,13R)-, (12S,13R)-, (12S,13S)- and (12R,13S)-8,13-epoxy-14-labden-12-ols (6-9) and (12S,13S)- and (12S,13R)-8,12-epoxy-14-labden-13-ols (3,4).Horseradish peroxidase also transformed (Z)-abienol into these products.