882491-37-4

Basic information

• Product Name: (6S)-6-hydroxy-3-[(1E)-3-hydroxy-3-methylpenta-1,4-dienyl]-2,4,4-trimethylcyclohex-2-en-1-one
• Synonyms: (6S)-6-hydroxy-3-[(1E)-3-hydroxy-3-methylpenta-1,4-dienyl]-2,4,4-trimethylcyclohex-2-en-1-one
• CAS NO: 882491-37-4
• Molecular Weight: 250.338
• Mol File: 882491-37-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (6S)-6-hydroxy-3-[(1E)-3-hydroxy-3-methylpenta-1,4-dienyl]-2,4,4-trimethylcyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (6S)-6-hydroxy-3-[(1E)-3-hydroxy-3-methylpenta-1,4-dienyl]-2,4,4-trimethylcyclohex-2-en-1-one(882491-37-4)
• EPA Substance Registry System: (6S)-6-hydroxy-3-[(1E)-3-hydroxy-3-methylpenta-1,4-dienyl]-2,4,4-trimethylcyclohex-2-en-1-one(882491-37-4)

Safety Data

• Hazardous Substances Data: 882491-37-4(Hazardous Substances Data)

Upstream product

• 83020-62-6 6-Hydroxy-3-(3'-hydroxy-3'-methyl-4'-penten-1'-inyl)-2,4,4-trimethyl-2-cyclohexen-1-on 
• 882491-36-3 C₁₅H₂₀O₃ 
• 74311-42-5 (S)-3-Acetoxy-4-oxo-β-jonon 
• 74285-59-9 (E)-3,5,5-trimethyl-2-oxo-4-(3-oxobut-1-en-1-yl)cyclohex-3-en-1-yl acetate 
• 74311-44-7 (S)-3-Hydroxy-4-oxo-β-jonon 
• 74285-61-3 (+/-)-3-Hydroxy-4-oxo-β-jonon 
• 74285-60-2 (+/-)-3-Acetoxy-4-oxo-β-jonon-9-(aethylenacetal) 
• 80713-56-0 4-Oxo-β-jonon-4,9-bis(aethylenacetal) 
• 69659-83-2 4-Oxo-β-jonon-9-(aethylenacetal) 
• 29790-29-2 (E)-2,4,4-trimethyl-3-(3-oxobut-1-en-1-yl)cyclohex-2-enone 
• 79-77-6 (E)-β-ionone 

Relevant articles and documents

6-HYDROXY-3-[3-HYDROXY-3-METHYL-PENTA-1,4-DIENYL]-2,4,4-TRIMETHYL-CYCLOHEXA-2,5-DIEN-1-ONE

The present invention relates to a process for preparing 6-hydroxy-3-[3-hydroxy-3- methyl-penta-1,4-dienyl]-2,4,4-trimethyl-cyclohexa-2,5-dien-1 -one of the formula (I). The invention also relates to 6-hydroxy-3-[3-hydroxy-3-methyl-penta-1,4-dienyl]-2,4,4

Synthese von Astaxanthin aus β-Jonon. I. Erschliessung der enantiomeren C15-Wittigsalze durch chemische und mikrobiologische Racematspaltung von (+/-)-3-Acetoxy-4-oxo-β-jonon

Racemic 3-acetoxy-4-oxo-β-ionone (10) was synthesized from the industrially accessible intermediate β-ionone (5).Resolution of 10 into its enantiomers was achieved via the corresponding diastereometric camphanates and by microbial resolution.Site-selective alkylation of racemic and of optically pure 3-acyloxy-4-oxo-β-ionones with vinyl magnesium chloride at -70 deg furnished the corresponding 3-acyloxy-4-oxo-9-vinyl-β-ionols which could be transformed to the Wittig salts 1, 3 and 4, respectively, following known procedures .