88270-69-3Relevant articles and documents
Efficient diacetoxylation of alkenes via Pd(II)/Pd(IV) process with peracetic acid and acetic anhydride
Park, Chan Pil,Lee, Joo Ho,Yoo, Kyung Soo,Jung, Kyung Woon
, p. 2450 - 2452 (2010)
A palladium-catalyzed diacetoxylation of alkenes in the presence of peracetic acid and acetic anhydride was developed to produce diacetates efficiently and diastereoselectively. Due to its mild conditions, this method was suitable for a broad range of substrates encompassing conjugated and nonconjugated olefins.
Metal-free, organocatalytic syn diacetoxylation of alkenes
Zhong, Wenhe,Liu, Shan,Yang, Jun,Meng, Xiangbao,Li, Zhongjun
supporting information; experimental part, p. 3336 - 3339 (2012/08/29)
A novel method for the organocatalytic syn diacetoxylation of alkenes has been developed using aryl iodides as efficient catalysts. A broad range of substrates, including electron-rich as well as electron-deficient alkenes, are smoothly transformed by the new procedure, furnishing the desired products in good to excellent yields with high diastereoselectivity (up to >19:1 dr).
Bis(NHC)-palladium(II) complex-catalyzed dioxygenation of alkenes
Wang, Wenfeng,Wang, Feijun,Shi, Min
experimental part, p. 928 - 933 (2010/05/01)
Bis(NHC)-Pd(II) complexes derived from l,l'-binaphthyl-2,2'-diamine (BINAM) were successfully first used to catalyze the dioxygenation of alkenes under mild conditions tolerant of air and moisture. Cationic NHC-Pd2+ diaquo complex 1e showed the highest catalytic activity to give 1,2dioxygenation products with good syn-diastereoselectivity for 1,2-disubstituted alkenes.
