88335-93-7 Usage
Description
6-Methoxycarbonyl-3-cyclohexene-1-carboxylic acid, also known as (1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester, is an organic compound with a cyclohexene ring and carboxylic acid functional groups. It possesses a methoxycarbonyl group attached to the 6th position and a monomethyl ester group at the 1st position. 6-Methoxycarbonyl-3-cyclohexene-1-carboxylic acid is known for its versatile chemical properties and potential applications in various industries.
Uses
Used in Organic Synthesis:
6-Methoxycarbonyl-3-cyclohexene-1-carboxylic acid is used as a starting material and intermediate in organic synthesis for the production of various chemical compounds. Its unique structure and functional groups make it a valuable building block for the synthesis of pharmaceuticals, agrochemicals, and other specialty chemicals.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 6-Methoxycarbonyl-3-cyclohexene-1-carboxylic acid is used as a key intermediate in the synthesis of drug candidates. Its presence in the molecular structure can impart specific biological activities, such as anti-inflammatory, analgesic, or antimicrobial properties, depending on the final compound's structure.
Used in Agrochemical Industry:
6-Methoxycarbonyl-3-cyclohexene-1-carboxylic acid is also utilized in the agrochemical industry as a precursor for the development of new pesticides and herbicides. Its chemical properties can be tailored to target specific pests or weeds, leading to more effective and environmentally friendly solutions.
Used in Specialty Chemicals:
In the specialty chemicals sector, 6-Methoxycarbonyl-3-cyclohexene-1-carboxylic acid is employed as a versatile intermediate for the production of various high-value compounds. These can include dyes, fragrances, and other specialty chemicals that are used in a wide range of applications, from cosmetics to industrial processes.
Overall, 6-Methoxycarbonyl-3-cyclohexene-1-carboxylic acid is a valuable compound with diverse applications across different industries, primarily due to its unique structure and functional groups that can be further modified and utilized in the synthesis of various chemical products.
Check Digit Verification of cas no
The CAS Registry Mumber 88335-93-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,8,3,3 and 5 respectively; the second part has 2 digits, 9 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 88335-93:
(7*8)+(6*8)+(5*3)+(4*3)+(3*5)+(2*9)+(1*3)=167
167 % 10 = 7
So 88335-93-7 is a valid CAS Registry Number.
InChI:InChI=1/C9H12O4/c1-13-9(12)7-5-3-2-4-6(7)8(10)11/h2-3,6-7H,4-5H2,1H3,(H,10,11)/t6-,7+/m1/s1
88335-93-7Relevant articles and documents
The New Catalyst System: Chloramphenicol Base and Organic Acid Co-catalyzed Enantioselective Alcoholysis of meso-Anhydride
Chen, Lu,Liu, Da-Ming,Ma, Chao,Sun, Chen,Wang, Zhong-Hua,Xiong, Fei,Zhang, Yan-Jun,Zhu, Yi-Ren
, p. 9 - 13 (2022/03/27)
In this study, the synergistic catalytic strategy was developed, which chloramphenicol base and organic acid were used in the same system, the optimal enantioselectivity value and yield (96% yield; 65% ee) was achieved using the binary co-catalyst in the asymmetric alcoholysis reaction of mesoanhydride. Moreover, a hypothetical intermediate between the substrate and the binary co-catalyst which is responsible for stereochemistry control in this catalytic reaction was proposed. In addition, the results of molecular mechanics calculations also have shed light on the corresponding catalytic mechanism.
Novel amide-functionalized chloramphenicol base bifunctional organocatalysts for enantioselective alcoholysis of meso-cyclic anhydrides
Xu, Lingjun,Han, Shuwen,Yan, Linjie,Wang, Haifeng,Peng, Haihui,Chen, Fener
, p. 309 - 317 (2018/02/19)
A family of novel chloramphenicol base-amide organocatalysts possessing a NH functionality at C-1 position as monodentate hydrogen bond donor were developed and evaluated for enantioselective organocatalytic alcoholysis of meso-cyclic anhydrides. These structural diversified organocatalysts were found to induce high enantioselectivity in alcoholysis of anhydrides and was successfully applied to the asymmetric synthesis of (S)-GABOB.
Reversible Switching and Recycling of Adaptable Organic Microgel Catalysts (Microgelzymes) for Asymmetric Organocatalytic Desymmetrization
Borrmann, Ruediger,Palchyk, Volodymyr,Pich, Andrij,Rueping, Magnus
, p. 7991 - 7996 (2018/09/18)
Adaptable enzyme-mimetic catalysts based on temperature-responsive polymer microgels (microgelzymes) have been developed. By a simple change in the temperature, a microgel catalyst can be reversibly switched into its soluble or precipitated form, thus com
