88358-45-6Relevant articles and documents
A Method for Mild Photochemical Oxidation; Conversion of Phenacyl Sulfides into Carbonyl Compounds
Vedejs, E.,Perry, D. A.
, p. 573 - 575 (2007/10/02)
Sunlamp irradiation of phenacyl sulfides PhCOCH2SCHRR' affords thiocarbonyl compounds S=CRR' that can be trapped in high yield by using the nitronate CH3CH=N+(OTBS)O-; the heterocycle 3 resulting from 1,3-dipolar cycloaddition is cleaved rapidly by fluoride ion to give ketones or aldehydes.