88444-72-8

Basic information

• Product Name: 1-Propanol, 2-cyclohexylidene-
• Synonyms: 1-Propanol, 2-cyclohexylidene-
• CAS NO: 88444-72-8
• Molecular Formula: C₉H₁₆O
• Molecular Weight: 140.22
• Mol File: 88444-72-8.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 224.4°C at 760 mmHg
• Flash Point: 93.4°C
• Appearance: /
• Density: 0.961g/cm³
• Vapor Pressure: 0.0183mmHg at 25°C
• Refractive Index: 1.497
• CAS DataBase Reference: 1-Propanol, 2-cyclohexylidene-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanol, 2-cyclohexylidene-(88444-72-8)
• EPA Substance Registry System: 1-Propanol, 2-cyclohexylidene-(88444-72-8)

Safety Data

• Hazardous Substances Data: 88444-72-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H16O/c1-8(7-10)9-5-3-2-4-6-9/h10H,2-7H2,1H3

Upstream product

• 131436-16-3 3-(hydroxymethyl)-3-methyloxetan-2-one-4-spirocyclohexane 
• 108-94-1 cyclohexanone 
• 121821-93-0 3-methyl-1-oxaspiro<3.5>nonan-2-one 
• 63963-01-9 ethyl 2-cyclohexilidenepropionate 

Downstream Products

• 110914-79-9 2-butoxy-4-(1-cyclohexenyl)-4-methyltetrahydrofuran 
• 306326-79-4 4-cyclohexylidene-2-methylpent-1-en-3-ol 
• 264879-08-5 4-cyclohexylidene-2-methylpent-1-en-3-one 
• 264879-09-6 4-cyclohexylidenepent-1-en-3-one 
• 7071-29-6 4-cyclohexylidenepent-1-en-3-ol 
• 7062-12-6 2-(cyclohexylidene)propionaldehyde 
• 3908-31-4 1-Isopropenyl-1-cyclohexanol 

Relevant articles and documents

Synthesis of All-Carbon Quaternary Centers by Palladium-Catalyzed Olefin Dicarbofunctionalization

The redox-neutral dicarbofunctionalization of tri- and tetrasubstituted olefins to form a variety of (hetero)cyclic compounds under photoinduced palladium catalysis is described. This cascade reaction process was used to couple styrenes or acryl amides with a broad range of highly decorated olefins tethered to aryl or alkyl bromides (>50 examples). This procedure enables one or two contiguous all-carbon quaternary centers to be formed in a single step. The products could be readily diversified and applied in the synthesis of a bioactive oxindole analogue.

Nazarov cyclization of 4-cycloalkylidene-5-(trimethylsilyl)pent-1-en-3-one derivatives. Synthesis of spiro[4.5]decane, Spiro[4.4]nonane, and Their derivatives

Spiro[4.5]decane and spiro[4.4]nonane ring systems were synthesized by FeCl3-induced Nazarov cyclization of α-(trimethylsilylmethyl)divinyl ketone derivatives. It was found that the double bond position of the product is controlled by the presence/absence of α'-substituent, while trimethylsilyl group is essential to obtain the products in good yields. Spiro[4.4]nonanes having exo-methylene group underwent rearrangement to bicyclo[4.3.0]nonanes. (C) 2000 Elsevier Science Ltd.