88491-17-2

Basic information

• Product Name: diprop-2-en-1-yl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate
• Synonyms: diprop-2-en-1-yl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate
• CAS NO: 88491-17-2
• Molecular Weight: 250.295
• Mol File: 88491-17-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: diprop-2-en-1-yl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: diprop-2-en-1-yl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate(88491-17-2)
• EPA Substance Registry System: diprop-2-en-1-yl (1R,2S)-cyclohex-4-ene-1,2-dicarboxylate(88491-17-2)

Safety Data

• Hazardous Substances Data: 88491-17-2(Hazardous Substances Data)

Upstream product

• 2305-26-2 cis-1,2,3,6-tetrahydrophthalic acid 
• 106-95-6 allyl bromide 

Relevant articles and documents

Titanium isopropoxide promoted tandem self-cross and ring-closing metathesis approach for the synthesis of macrotetralides

A new approach is demonstrated for the synthesis of macrotetralides through an olefin metathesis reaction using Grubbs' second-generation catalyst with titanium isopropoxide as a cocatalyst. This study demonstrates a tandem self-cross and ring-closing metathesis approach to form macrocyclic ring systems with excellent (E) selectivity. The reaction was optimized with regard to functional group, catalyst, solvent, Lewis acid, concentration, and temperature. A new approach is demonstrated for the synthesis of macrotetralides through tandem self-cross and ring-closing metathesis reactions using Grubbs' second-generation catalyst and titanium isopropoxide. Copyright