88618-52-4

Basic information

• Product Name: Phosphonic acid, (3-nitrophenyl)-, bis(1-methylethyl) ester
• CAS NO: 88618-52-4
• Molecular Formula: C12H18NO5P
• Molecular Weight: 287.252
• Mol File: 88618-52-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, (3-nitrophenyl)-, bis(1-methylethyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, (3-nitrophenyl)-, bis(1-methylethyl) ester(88618-52-4)
• EPA Substance Registry System: Phosphonic acid, (3-nitrophenyl)-, bis(1-methylethyl) ester(88618-52-4)

Safety Data

• Hazardous Substances Data: 88618-52-4(Hazardous Substances Data)

Upstream product

• 1809-20-7 diisopropyl hydrogenphosphonate 
• 13331-27-6 m-nitrobenzene boronic acid 
• 5337-19-9 (m-nitrophenyl)phosphonic acid 
• 34909-17-6 (3-nitrophenyl)phosphonic dichloride 
• 67-63-0 isopropyl alcohol 

Downstream Products

• 89277-86-1 diisopropyl 3-aminophenylphosphonate 

Relevant articles and documents

Cobalt catalyzed C-P bond formation by cross-coupling of boronic acids with P(O)H compounds in presence of zinc

In our current work, we have reported the first cobalt-catalyzed cross-coupling of arylboronic acid with alkyl/aryl phosphites under mild conditions. The reaction was carried out in the presence of zinc powder as an additive and ter-pyridine as a ligand. The use of non-precious cobalt salt makes the protocol advantageous, as it is inexpensive and more abundant than the previously used methods where precious metal salts (Pd and Pt) were used. The reaction has a wide substrate scope and the products were obtained in good yields.

SYNTHESIS OF SOME DIALKYL ESTERS OF M-NITROBENZENEPHOSPHONIC ACID.

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