88635-40-9

Basic information

• Product Name: [(η⁶-p-cymene)RuCl₂(η¹-bis(diphenylphosphino)methane)]
• Synonyms: [(η⁶-p-cymene)RuCl₂(η¹-bis(diphenylphosphino)methane)]
• CAS NO: 88635-40-9
• Molecular Weight: 690.594
• Mol File: 88635-40-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: [(η⁶-p-cymene)RuCl₂(η¹-bis(diphenylphosphino)methane)](CAS DataBase Reference)
• NIST Chemistry Reference: [(η⁶-p-cymene)RuCl₂(η¹-bis(diphenylphosphino)methane)](88635-40-9)
• EPA Substance Registry System: [(η⁶-p-cymene)RuCl₂(η¹-bis(diphenylphosphino)methane)](88635-40-9)

Safety Data

• Hazardous Substances Data: 88635-40-9(Hazardous Substances Data)

Upstream product

• 2071-20-7 bis-diphenylphosphinomethane 
• 52462-29-0 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 

Downstream Products

• 88611-20-5 C₄₅H₅₀Cl₄P₂Ru₂ 
• 240803-86-5 [(η(6)-cymene)RuCl2(η(1)-Ph2PCH2P(O)Ph2)] 
• 599199-20-9 [(η6-p-cymene)(η2-bis(diphenylphosphino)methane)RuCl]Cl 

Relevant articles and documents

Facile entry to germanate and stannate complexes [(η6-arene)RuCl(η2-dppm)]+[ECl3]- (E = Ge, Sn) as potent anti-cancer agents

A series of arene Ru(II) salt complexes of the type [(η6-arene)RuCl(η2-dppm)]+[ECl3]- (arene = C6H6, p-cymene, 1,3,5-Me3C6H3; E = Ge, Sn) bearing

Design, synthesis and characterisation of new chimeric ruthenium(ii)-gold(i) complexes as improved cytotoxic agents

Two heterobimetallic complexes, i.e. [RuCl2(p-cymene)(μ-dppm)AuC] (1) and [RuCl2(p-cymene)(μ-dppm)Au(S-thiazoline)] (3), based on known cytotoxic [Ru(p-cymene)Cl2(PR3)] and [AuX(PR3)] (X = Cl, SR) mol

Dehalogenation of binuclear arene-ruthenium complexes: A new route to homonuclear triruthenium and heteronuclear ruthenium-iron cluster complexes containing chelating phosphorus ligands. Crystal structure of Ru3(CO)10(Ph2PCH2PPh2)

The binuclear complexes (RuCl2(p-cymene))2(Ph2P(CH2) nPPh2) (2, n = 2; 4, n = 1) obtained from (RuCl2(p-cymene))2 have been reacted with an excess of Fe2(CO)9. The former derivative, 2, yielded FeRu(CO)8(Ph2PCH2CH2PPh2) (5), (Fe2Ru(μ-CO)2(CO)9)2(Ph 2PCH2CH2PPh2) (6), Ru3(μ-Cl)2(CO)8(Ph2PCH 2CH2PPh2) (7), and FeRu2(μ-Cl)2(CO)8(Ph2PCH 2CH2PPh2) (8) (noticeably, thermolysis of 8 under mild conditions yielded 7). The latter derivative, 4, afforded Ru3(CO)10(Ph2PCH2PPh2) (9) and FeRu2(CO)10(Ph2PCH2PPh2) (10). The X-ray crystal structure of 9 has been determined: monoclinic crystals, space group P21/c with a = 13.122 (3) A?, b = 12.040 (4) A?, c = 23.658 (7) A?, β = 103.44 (2)°, and Z = 4. Final R and Rw values are respectively 0.036 and 0.041 on the basis of 4346 independent reflections. The Ph2PCH2PPh2 group that bridges a Ru-Ru bond occupies equatorial positions. Interatomic distances of interest are Ru(1)-Ru(2) = 2.834 (1), Ru(1)-Ru(3) = 2.841 (1), and Ru(2)-Ru(3) = 2.860 (1) A?. The shortest bond Ru(1)-Ru(2) is supported by the chelating phosphorus ligand (Ru(1)-P(1) = 2.322 (2) and Ru(2)-P(2) = 2.334 (2) A?). Ru-P bonds are not coplanar as shown by the dihedral angle P(1)-Ru(1)-Ru(2)/P(2)-Ru(2)-Ru(1) = 19.1 (1)°. Such a distortion induces a disturbance in the distribution of CO ligands with respect to Ru3(CO)12. Of particular interest is the bending of every axial carbonyl toward one Ru-Ru bond.