887642-50-4

Basic information

• Product Name: N-benzyl-2-hydroxy-2-p-tolylacetamide
• CAS NO: 887642-50-4
• Molecular Weight: 255.316
• Mol File: 887642-50-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzyl-2-hydroxy-2-p-tolylacetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-2-hydroxy-2-p-tolylacetamide(887642-50-4)
• EPA Substance Registry System: N-benzyl-2-hydroxy-2-p-tolylacetamide(887642-50-4)

Safety Data

• Hazardous Substances Data: 887642-50-4(Hazardous Substances Data)

Upstream product

• 88333-03-3 Benzyl isocyanide 
• 104-87-0 4-methyl-benzaldehyde 
• 887642-30-0 N-benzyl-2-hydroxy-2-p-tolylacetamide 

Relevant articles and documents

Asymmetric aerobic oxidation of α-hydroxy acid derivatives catalyzed by reusable, polystyrene-supported chiral N-salicylidene oxidovanadium tert-leucinates

The direct immobilization of two different C-5-propargyl ether-modified, chiral N-salicylidene vanadyl(V) tert-leucinates onto 4-azidomethyl-substituted polystyrene by click chemistry was examined. Among the eight different solvents investigated, the resulting polystyrene-supported catalysts promote the asymmetric, aerobic oxidation of α-hydroxy (thio)esters and amides with enantioselectivities of up to 99% ee (selectivity factor up to 41) in chloroform. These polystyrene-supported catalysts can be readily recovered by filtration and reused for at least four consecutive runs without discernible loss of reactivity and enantioselectivity.