88766-86-3

Basic information

• Product Name: Silane, trimethyl[[1-(2-phenylethyl)-1-heptenyl]oxy]-, (E)-
• CAS NO: 88766-86-3
• Molecular Formula: C18H30OSi
• Molecular Weight: 290.521
• Mol File: 88766-86-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[[1-(2-phenylethyl)-1-heptenyl]oxy]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[[1-(2-phenylethyl)-1-heptenyl]oxy]-, (E)-(88766-86-3)
• EPA Substance Registry System: Silane, trimethyl[[1-(2-phenylethyl)-1-heptenyl]oxy]-, (E)-(88766-86-3)

Safety Data

• Hazardous Substances Data: 88766-86-3(Hazardous Substances Data)

Upstream product

• 88766-76-1 1-phenyl-3-(trimethylsilyl)-4-nonen-3-ol 
• 61157-31-1 3-phenylpropionyltrimethylsilane 
• 13154-16-0 1-hexenylmagnesium bromide 

Relevant articles and documents

BASE-INDUCED REARRANGEMENT OF 1-(TRIMETHYLSILYL)ALLYLIC ALCOHOLS. STEREO- AND REGIOSELECTIVE SYNTHESIS OF SILYL ENOL ETHERS THROUGH LITHIUM HOMOENOLATES.

1-(Trimethylsilyl)allylic alcohols have been prepared and their conversions to silyl enol ethers have been examined. Under appropriate conditions, lithium alkoxides of the above alcohols are in equilibrium with lithium homoenolates, 3-(trimethylsiloxy)allyllithiums, which react with alkyl iodides to give the silyl enol ethers of defined stereo- and regiochemistry. Further, a catalytic amount of butyllithium induces the rearrangement of the alcohols to yield the corresponding silyl enol ethers in a highly stereo- and regiocontrolled manner via self-protolysis. Equilibrium composition between lithium alkoxides and lithium homoenolates has been shown to be greatly influenced by the steric factors around alpha carbons of allylic alcohols.