889132-63-2Relevant articles and documents
Limitations, mechanism and understanding of the origins of stereocontrol in (S)-dimethylsulfonium-(p-tolylsulfinyl)methylide-mediated epoxidation reactions
Midura, Wanda H.,Cypryk, Marek
experimental part, p. 177 - 186 (2010/04/29)
The reaction of the (S)-dimethylsulfonium-(p-tolylsulfinyl)methylide with aldehydes gave α,β-epoxy sulfoxides with high enantioselectivity and diastereoselectivity dependent on the aldehyde. The mechanism of the 'model' reactions [ylide substituted with M