89051-52-5

Basic information

• Product Name: p-nitrobenzyl 2β-(chloromethyl)-2α-methylpenam-3α-carboxylate
• Synonyms: p-nitrobenzyl 2β-(chloromethyl)-2α-methylpenam-3α-carboxylate
• CAS NO: 89051-52-5
• Molecular Weight: 370.813
• Mol File: 89051-52-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: p-nitrobenzyl 2β-(chloromethyl)-2α-methylpenam-3α-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: p-nitrobenzyl 2β-(chloromethyl)-2α-methylpenam-3α-carboxylate(89051-52-5)
• EPA Substance Registry System: p-nitrobenzyl 2β-(chloromethyl)-2α-methylpenam-3α-carboxylate(89051-52-5)

Safety Data

• Hazardous Substances Data: 89051-52-5(Hazardous Substances Data)

Upstream product

• 71355-12-9 p-nitrobenzyl <(R)-4-(2-benzothiazol-2-yldithio)-2-oxo-1-azetidinyl>isopropenylacetate 
• 71355-11-8 2,2-dimethylpenam-3α-carboxylic acid 1-oxide p-nitrobenzyl ester 
• 104102-09-2 (R)-3-Methyl-2-[2-(5-{1-[(R)-2-methyl-1-(4-nitro-benzyloxycarbonyl)-allyl]-4-oxo-azetidin-2-yldisulfanyl}-[1,3,4]thiadiazol-2-yldisulfanyl)-4-oxo-azetidin-1-yl]-but-3-enoic acid 4-nitro-benzyl ester 

Relevant articles and documents

A facile halogenative cyclization of 4-(2-benzothioazolyldithio)azetidinones (Kamiya's disulfide) into 2β-(halomethyl)penams in a two layer system

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THE TRAPPING OF SULFENIC ACIDS FROM PENICILLIN SULFOXIDES. HETEROCYCLIC MERCAPTANS

Various heterocyclic thiols have been used for trapping the azetidinone sulfenic acids obtained by the thermolysis of penicillin sulfoxides.The ester function was found to be important in determining the unsym-azetidinone disulfide (α,β- or β,γ-unsaturated) isomer formed.All β,γ-isomers prepared reacted with cupric chloride to give the 2-chloromethylpenams.