89056-02-0Relevant articles and documents
Sulfosilylation of Carbonyl Compounds and Trimethylsilyl Enol Ethers with Trimethylsilyl Chlorosulfonate
Hofmann, Karin,Simchen, Gerhard
, p. 39 - 47 (2007/10/02)
Aldehydes and ketones 3 react with trimethylsilyl chlorosulfonate (1a) to yield trimethylsilyl 2-oxosulfonates 5.The course of this sulfosilylation is discussed briefly.The sulfosilylation of trimethylsilyl carboxylates 7 and trimethylsilyl ketene acetals 14 results in formation of 2-(trimethylsiloxysulfonyl)carboxylates 8 and 15.