893397-17-6Relevant articles and documents
Stable M(II)-Radicals and Nickel(III) Complexes of a Bis(phenol) N-Heterocyclic Carbene Chelated to Group 10 Metal Ions
Kunert, Romain,Philouze, Christian,Jarjayes, Olivier,Thomas, Fabrice
, p. 8030 - 8044 (2019/06/17)
The tetradentate ligand based on (1-imidazolium-3,5-ditert-butylphenol) units was prepared and chelated to group 10 metal ions (Ni(II), Pd(II), and Pt(II)), affording complexes 1, 2, and 3, respectively. The X-ray crystal structures of 1-3 show a square p
Electrochemical synthesis of 2-aryl-2H-benzotriazoles and their N-oxides by controlled potential cathodic electrolysis
Kim, Byeong Hyo,Lee, Doo Byung,Kim, Dae Ho,Han, Rongbi,Jun, Young Moo,Baik, Woonphil
, p. 841 - 850 (2007/10/03)
Using a divided cell, reductive cyclizations of o-nitrophenylazo dyes (1) toward 2-aryl-2H-benzotriazole-1-oxides (2) or 2-aryl-2H-benzotriazoles (3) were successfully accomplished by the controlled potential cathodic electrolysis reactions. 1 was transformed to 2 under neutral conditions while 1 was transformed to 3 under basic conditions.