893752-56-2

Basic information

• Product Name: 2-(m-tolyloxy)benzaldehyde
• Synonyms: 2-(m-tolyloxy)benzaldehyde
• CAS NO: 893752-56-2
• Molecular Weight: 212.248
• Mol File: 893752-56-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-(m-tolyloxy)benzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(m-tolyloxy)benzaldehyde(893752-56-2)
• EPA Substance Registry System: 2-(m-tolyloxy)benzaldehyde(893752-56-2)

Safety Data

• Hazardous Substances Data: 893752-56-2(Hazardous Substances Data)

Upstream product

• 108-39-4 3-methyl-phenol 
• 6630-33-7 ortho-bromobenzaldehyde 
• 1416276-98-6 bis(3-methylphenyl)iodonium trifluoromethanesulfonate 
• 71730-46-6 benzo[e][1,2,3]oxathiazine 2,2-dioxide 
• 89-98-5 2-chloro-benzaldehyde 
• 446-52-6 2-Fluorobenzaldehyde 

Downstream Products

• 19814-98-3 3-methyl-9H-xanthen-9-one 
• 84273-41-6 1-Methyl-9H-xanthen-9-one 
• 620-46-2 3'-methylphenyl salicylate 

Relevant articles and documents

Stereoselective synthesis of 9-vinyl substituted unsymmetrical xanthenes and thioxanthenes

Activated 2°-allylic alcohols derived from 2-aryloxybenzaldehydes and 2-(arythio)benzaldehydes undergo intramolecular Friedel-Crafts alkylation reaction when heated with catalytic amount of a Lewis acid in 1,2-dichloroethane to provide highly E-selective 9-vinyl substituted unsymmetrical novel xanthenes and thioxanthenes in good yields.

Tert -Butoxide mediated cascade desulfonylation/arylation/hydrolysis of cyclic sulfonyimines using diaryliodonium salts: Synthesis of diaryl ether derivatives bearing a 2-aldehyde group

Cascades of cyclic sulfonyimines mediated by tBuOK with diaryliodonium salts has been developed, giving the diaryl ethers in good yields. Furthermore, bulky ortho-substituted diaryl ethers with an aldehyde group can be obtained easily in comparision with metal-catalyzed protocols.

Cross dehydrogenative coupling via base-promoted homolytic aromatic substitution (BHAS): Synthesis of fluorenones and xanthones

Cross dehydrogenative coupling reactions occurring via base-promoted homolytic aromatic substitutions (BHASs) are reported. Fluorenones and xanthones are readily prepared via CDC starting with readily available ortho-formyl biphenyls and ortho-formyl biphenylethers, respectively. The commercially available and cheap tBuOOH is used as an oxidant. Initiation of the radical chain reaction is best achieved with small amounts of FeCp2 (0.1 or 1 mol %).