89444-36-0Relevant articles and documents
Copper-catalyzed aerobic aliphatic C-H oxygenation with hydroperoxides
Too, Pei Chui,Tnay, Ya Lin,Chiba, Shunsuke
supporting information, p. 1217 - 1225 (2013/07/26)
We report herein Cu-catalyzed aerobic oxygenation of aliphatic C-H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carboncentered radicals with molecular oxygen.
The Heterogeneous Catalytic Hydrogenation of Cumulated Allene-cyclopropanes: 1-(2'-Methylpropenylidene)-2-phenylcyclopropane.
Cromble, Leslie,Fernando, Candida E. C.
, p. 1519 - 1537 (2007/10/03)
The unsymmetrical title compound 2 having phenyl as an activating substituent was hydrogenated in heterogeneous solution phase using supported platinum and palladium as well as Raney nickel catalysts. Data are presented graphically using 'snapshot analysi