89455-82-3Relevant articles and documents
Hydrophosphination of alkoxyalkenes catalyzed by transition metal complexes
Shulyupin,Trostyanskaya,Kazankova,Beletskaya
, p. 17 - 22 (2007/10/03)
Diphenylphosphine adds to alkyl vinyl ethers in the presence of Ni(II) and Pd(II) complexes with a high regioselectivity, leading to exclusive formation of the corresponding Markownikoff adducts which were isolated as 1-alkoxyalkyl(diphenyl)phosphine oxid
WITTIG AND HORNER-WITTIG COUPLING REACTIONS OF 2-SUBSTITUTED CYCLIC ETHERS AND THEIR APPLICATION TO SPIROKETAL SYNTHESIS
Ley, Steven V.,Lygo, Barry,Organ, Helen M.,Wonnacott, Anne
, p. 3825 - 3836 (2007/10/02)
Wittig and Horner-Wittig coupling reactions of tetrahydropyran or tetrahydrofuran 2-triphenylphosphonium salts or 2-diphenylphosphine oxides with aldehydes and lactols affords good yields of the corresponding enol ethers.In selected examples these enol ether products may be further converted to spiroketals some of which are natural pheromones derived from Dacus oleae and Paravespula vulgaris.