89469-84-1

Basic information

• Product Name: Acetamide, N-[2-[5-(acetyloxy)-3,6-dimethoxy-4-phenanthrenyl]ethyl]-N-methyl-
• CAS NO: 89469-84-1
• Molecular Formula: C23H25NO5
• Molecular Weight: 395.455
• Mol File: 89469-84-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetamide, N-[2-[5-(acetyloxy)-3,6-dimethoxy-4-phenanthrenyl]ethyl]-N-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, N-[2-[5-(acetyloxy)-3,6-dimethoxy-4-phenanthrenyl]ethyl]-N-methyl-(89469-84-1)
• EPA Substance Registry System: Acetamide, N-[2-[5-(acetyloxy)-3,6-dimethoxy-4-phenanthrenyl]ethyl]-N-methyl-(89469-84-1)

Safety Data

• Hazardous Substances Data: 89469-84-1(Hazardous Substances Data)

Upstream product

• 115-37-7 thebaine 
• 108-24-7 acetic anhydride 
• 91295-73-7 Δ^5,7,9(14)-N-Acetyldesthebaine 

Relevant articles and documents

Thebaine Rearrangements: Nonclassical D Ring Migrations

3,6-Dimethoxy-4-acetoxy-5-phenanthrene (3) and its isomer 3,6-dimethoxy-4-acetoxy-8-phenanthrene (4) have been detected as manufacturing byproducts at trace levels in illicit heroin.These compounds are novel rearrangement products obtained by the action of acetic anhydride (Ac2O) on thebaine (1).The syntheses of 3 and 4 from 1 proceed via the intermediate Δ5,7,9(14)-N-acetyldesthebaine (2).Structural characterization and optimization of synthetic conditions for 3 and 4 are described.A brief discussion is also giving concerning other neutral products of 1 obtained under Ac2O conditions.